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Bundesliga 
1′ K. Behrens (Assist: J. Roussillon)- 9′ K. Behrens (Assist: A. Laidouni)
- 11′ K. Behrens
31′ Lee Jae-Sung 
51′ D. Kohr 
59′ D. da Costa 
60′ S. van den Berg
D. Kohr
60′ B. Gruda
K. Onisiwo
63′ L. Ajorque (Missed penalty)
64′ A. Caci
66′ R. Gosens
J. Roussillon
66′ S. Becker
D. D. Fofana- 70′ K. Behrens (Assist: S. Becker)
75′ A. Barkok
Lee Jae-Sung
76′ M. Pantovic
B. Aaronson
80′ L. Barreiro 
81′ T. Krauss
A. Stach
81′ N. Weiper
D. da Costa- 88′ L. Ajorque (Missed penalty)
89′ K. Volland
K. Behrens
89′ A. Kemlein
A. Laidouni- 90′ S. van den Berg
- 90′ M. Pantovic (Assist: K. Volland)
Vote for winner:
52
Votes
4
Votes
Previous matches:
| Union Berlin | 4 | 1 | Mainz 05 |
| Bundesliga - 20.08.2023 | |||
| Union Berlin | 2 | 1 | Mainz 05 |
| Bundesliga - 04.02.2023 | |||
| Mainz 05 | 0 | 0 | Union Berlin |
| Bundesliga - 14.08.2022 | |||
| Union Berlin | 3 | 1 | Mainz 05 |
| Bundesliga - 26.02.2022 | |||
| Mainz 05 | 1 | 2 | Union Berlin |
| Bundesliga - 03.10.2021 | |||
| Mainz 05 | 1 | 0 | Union Berlin |
| Bundesliga - 06.02.2021 | |||
| Union Berlin | 4 | 0 | Mainz 05 |
| Bundesliga - 02.10.2020 | |||
| Union Berlin | 1 | 1 | Mainz 05 |
| Bundesliga - 27.05.2020 | |||
| Mainz 05 | 2 | 3 | Union Berlin |
| Bundesliga - 09.11.2019 | |||
| Union Berlin | 1 | 1 | Mainz 05 |
| Bundesliga 2 - 31.01.2004 | |||
| Mainz 05 | 2 | 1 | Union Berlin |
| Bundesliga 2 - 02.08.2003 | |||
| Mainz 05 | 1 | 0 | Union Berlin |
| Bundesliga 2 - 25.01.2003 | |||
| Union Berlin | 0 | 2 | Mainz 05 |
| Bundesliga 2 - 09.08.2002 | |||
| Union Berlin | 3 | 1 | Mainz 05 |
| Bundesliga 2 - 04.05.2002 | |||
| Mainz 05 | 1 | 0 | Union Berlin |
| Bundesliga 2 - 15.12.2001 | |||